Database : Guidelines for Application-Specific Indexes

You can create indexes on columns to speed up queries. Indexes provide faster access to data for operations that return a small portion of a table's rows.

In general, you should create an index on a column in any of the following situations:

• The column is queried frequently.
• A referential integrity constraint exists on the column.
• A UNIQUE key integrity constraint exists on the column.

You can create an index on any column; however, if the column is not used in any of these situations, creating an index on the column does not increase performance and the index takes up resources unnecessarily.

Although the database creates an index for you on a column with an integrity constraint, explicitly creating an index on such a column is recommended.

You can use the following techniques to determine which columns are best candidates for indexing:

• Use the EXPLAIN PLAN feature to show a theoretical execution plan of a given query statement.
• Use the V$SQL_PLAN view to determine the actual execution plan used for a given query statement.

Sometimes, if an index is not being used by default and it would be most efficient to use that index, you can use a query hint so that the index is used.

https://docs.oracle.com/cd/B14117_01/appdev.101/b10795/adfns_in.htm